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This book focuses on chemical reactions in the crystalline state. Because the reactions cover a variety of fields in inorganic and organic chemistry, with more than 300 references, the book is an indispensable resource for inorganic, organic, and physical chemists and graduate students. The crystalline state reaction is a new category of solid state reaction, in which a reaction occurs with retention of the single crystal form. The whole reaction process can be observed directly by X-ray and neutron diffractions. Not only the structures of metastable intermediates, such as radicals, carbenes, and nitrenes, but also the metastable species of photochromic compounds and unstable photo-excited structures are shown with colored figures of the molecular structures.